How often does something go wrong?
Beyond turning kit on and off what do you expect to be able to do afloat? (I assume you aren’t going to have a heap of spares to swap out).
I’m no expert but I’d start just by mapping out what you have and understanding how it all connects etc, and keeping a record of all the configuration/admin passwords for each element and their settings so if you need to do a hard reset / replacement you can quickly reconfigure. e.g. the firewall doesn’t issue IP addresses, a DHCP server does – although it might live in the same box as the firewall. IF the firewall and DHCP server etc are Linux based you’ll find plenty of reading on line (or in books) on basic Linux server management. Once you’ve worked out what the DHCP server, gateway, wireless access point, etc are then you might want to make sure you understand subnet masks. After that TCP ports etc and port forwarding, network address translation etc. And if you are feeling good at that point then routing tables.
Once you’ve read about those and understood how they are set up and controlled on your network without buggering up the connection for everyone then you probably have a lot of stuff covered! 99% of your support questions will probably be for stupid things like not being able to type Pa55w0rd correctly!