50mm and primes rock.
The canon f1.8 lens is a great one to try. I had one and it eventually fell apart. I now have the f1.4. Somewhat pricier but much faster in focusing (USM motor). It works really nicely and is repairable for a price. I find the Bokeh on the f1.4 is nicer than the f1.8. It has more blades on the diaphragm (8 Vs 5).
Blurry background is the effect of depth of focus. With a lens like a f1.8 or lower you have to be careful that you don’t end up with things like an ear in focus and a blurry nose 😳
I think of bokeh as the patterning given to the out of focus stuff: a function of the depth of focus, aperture, light conditions and number of diaphragm blades.
On a 350D the 50mm lens will give you a field of view more like an 80mm lens would on a ‘regular’ film SLR. Even so, I find it’s the lens I use most. Far more than any zoom. The reason being there’s less faff in framing up (too small? move closer. Too big? Move away) and the low light performance and image quality is better than my zoom lenses.
A nice thing about using regular lenses on a compact sensor camera is that the edge of lens aberration is usually off the sensor.
If you’re really after the traditional field of view of a 50mm lens you’ll need to go to about 28-30mm. Those are a little pricier.